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News on wine stabilization

The science of enology continues to study the topic of wine stabilization. Essentially, the goal is to avoid the precipitation of wine crystals consisting of potassium bitartrate (potassium hydrogen tartrate) or calcium tartrate in the bottle....

The science of enology continues to study the topic of wine stabilization. Essentially, the goal is to avoid the precipitation of wine crystals consisting of potassium bitartrate (potassium hydrogen tartrate) or calcium tartrate in the bottle. Wine-drinkers are still averse to the presence of sediments in the wine glass (Fig. 1).

In the years 2018 and 2020, the following vinification variants were tested with respect to their stabilization properties (using 2017 and a 2019 Sauvignon Blanc):

  • Control without stabilization measures (C),

  • Cold stabilization (CS) at -4 °C for 2 weeks,

  • Metatartaric acid (MTA) 10 g/hl (only 2018 for 2017

    Sauvignon Blanc),

  • Carboxymethylcellulose (CMC) 10 g/hl

  • Potassium polyaspartate (PPA) 100 ml/hl and 50 ml/hl. 

The study was performed three times, with a size of about 10 L per sample.

The electrical conductivity (µS) of the wine was taken as a measure of the bitartrate stability; this was measured shortly after bottling and after 7, 14, and 21 weeks (Fig. 2) as well as after 52 weeks (Fig. 3). The Checkstab α2000 Life measuring device was used for these measurements. This device measures the change in conductivity (ΔµS) caused by unstable potassium bitartrate crystals, and thus simulates bitartrate stability. Stability is said to be present if the decline in conductivity is less than 40 µS. A drop in conductivity in the range of 40-60 µS is classified as uncertain stability, while a decrease of more than 60 µS indicates that the product is unstable.

The wines also underwent sensory testing. During the tasting, the following parameters were evaluated: Color, turbidity, purity, intensity, fruitiness, bitterness, typicity, developmental stage, and overall impression.

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Results The investigations indicate that cold stabilization is effective and, at the same time, does not impact wine quality. Analytically, a decline in potassium and potassium bitartrate in the wine was determined. This effect can be tasted, but...
Results

The investigations indicate that cold stabilization is effective and, at the same time, does not impact wine quality. Analytically, a decline in potassium and potassium bitartrate in the wine was determined. This effect can be tasted, but does not result in any reduction in the overall sensory quality. All other stabilization measures resulted in no significant change in the chemical composition of the wine, but some did have an influence upon its organoleptic characteristics (Fig. 4). The addition of metatartaric acid showed the already known shortcomings: Its effect vanishes within 6 months; thus, metatartaric acid provides only short-term protection against the precipitation of potassium bitartrate. Nevertheless, it remains the most used stabilizing agent in combination with prior more or less effective cold stabilization. CMC offers long-term stabilization, but with respect to sensory evaluations, it deviated the most negatively from the control and the cold-stabilized wines. PPA displayed no sensory shortcomings, but it was observed that the stabilization effect vanished after 12 months. The literature does not mention this effect; the cause for it is unknown and requires further investigation. Furthermore, long-term effects lasting for more than 12 months were not investigated in this study, nor was the effect of PPA on red wine.

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Summary One must come to the sobering conclusion that the methods of wine stabilization investigated here are not fully satisfactory. Cold stabilization has the largest CO2 footprint; the addition of metatartaric acid provides a maximum protection...
Summary

One must come to the sobering conclusion that the methods of wine stabilization investigated here are not fully satisfactory. Cold stabilization has the largest CO2 footprint; the addition of metatartaric acid provides a maximum protection of six months; carboxymethylcellulose can have noticeably negative sensory effects and is not to be used for red wine; Potassium polyaspartate can lose its protective properties after 12 months.

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